By Peter C., Ford
content material: Activation of carbon monoxide via carbon and oxygen coordination : Lewis acid and proton brought on aid of carbon monoxide / D.F. Shriver --
Experimental and theoretical stories of mechanisms within the homogeneous catalytic activation of carbon monoxide / H.M. Feder, J.W. Rathke, M.J. Chen, and L.A. Curtiss --
Heterobimetallic carbon monoxide hydrogenation : hydrogen move to coordinated acyls : the molecular constitution of (C₅H₅)₂Re[(C₅H₅)₂ZrCH₃](OCHCH₃) / John A. Marsella, John C. Huffman, and Kenneth G. Caulton --
strange carbon monoxide activation, aid, and homologation reactions of 5f-element organometallics --
The chemistry of carbene-like dihaptoacyls / Paul J. Fagan, Eric A. Maatta, and Tobin J. Marks --
Chemistry of the water fuel shift response catalyzed via rhodium complexes / T. Yoshida, T. Okano, and Sei Otsuka --
The water gasoline shift response as catalyzed through ruthenium carbonyl in acidic strategies / Peter C. Ford, Paul Yarrow, and Haim Cohen --
the significance of reactions of oxygen bases with steel carbonyl derivatives in catalysis : homogeneous catalysis of the water gasoline shift response / Donald J. Darensbourg and Andrzej Rokicki --
Homogeneous catalysis of the water fuel shift response utilizing easy mononuclear carbonyls / R.B. King, A.D. King, Jr., and D.B. Yang --
Homogeneous catalytic aid of benzaldehyde with carbon monoxide and water : functions of the water fuel shift response / William J. Thomson and Richard M. Laine --
Electrophile-induced disproportionation of the impartial formyl ([eta]-C₅H₅)Re(NO)(PPh₃)(CHO) : isolation and houses of the rhenium methylidene [([eta]-C₅H₅)Re(NO)(PPh₃)(CH₂)]PF₆⁻ / J.A. Gladysz, William A. Kiel, Gong-Yu Lin, Wai-Kwok Wong, and Wilson Tam --
Hydrocarbon formation on polymer-supported [eta]⁵-cyclopentadienyl cobalt / Linda S. Benner, Patrick Perkins, and okay. Peter C. Vollhardt --
Chain-length keep an eye on within the conversion of syngas over carbonyl compounds anchored right into a zeolite matrix / D. Ballivet-Tkatchenko, N.D. Chau, H. Mozzanega, M.C. Roux, and that i. Tkatchenko --
Hydrogenation of carbon monoxide on alumina-supported metals : a tunneling spectroscopy learn / R.M. Kroeker, P.K. Hansma, and W.C. Kaska --
Hydrogenation of carbon monoxide to methanol and ethylene glycol by means of homogeneous ruthenium catalysts / B. Duane Dombek --
Syngas homologation of aliphatic carboxylic acids / John F. Knifton --
Decarbonylation of aldehydes utilizing ruthenium(II) porphyrin catalysts / G. Domazetis, B.R. James, B. Tarpey, and D. Dolphin --
Reactions of ([eta]-C₅H₅)₂NbH₃ with steel carbonyls : selective aid of carbon monoxide to ethane / J.A. Labinger and K.S. Wong --
Formation of hydrocarbons via hydridic relief of carbon monoxide on Cp₂Fe₂(CO)₄ / Andrew Wong and Jim D. Atwood --
Selective conversion of carbonyl ligands on ([eta]₅-C₅H₅)Fe(CO)₃⁺ to C₂ natural compounds / Alan Cutler, Thomas Bodnar, Gene Coman, Stephen Lacroce, Carol Lambert, and Kevin Menard --
fragrant gas from hydrogen/carbon monoxide over ruthenium/zeolite catalysts / T.J. Huang and W.O. Haag --
Mechanistic facets of the homogeneous water gasoline shift response / W.A.R. Slegeir, R.S. Sapienza, and B. Easterling.
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Additional info for Catalytic Activation of Carbon Monoxide
Since dimer I I I contains a Zr-C bond of purely σ character, this bond length provides an i n t e r n a l standard f o r comparison of bond order. 37 A shorter than the Zr-CH bond; a s i g n i f i cant TT-component i s present i n t h i s Zr-OR bond. In Cp MXY complexes (M = T i , Zr, Hf), the ligands X and Y together donate a t o t a l of four electrons to the n e u t r a l fragment Cp M. When Y i s a ηοη-ττ-donor, as CH i n complex I I I , a l l π bonding i s provided by X(0R); t h i s leads to maximum contraction of the Zr-0 distance.
In view of the fact that early t r a n s i t i o n metal a l k y l s i n s e r t CO under very mild conditions (2,3), we chose to examine the reactions of e l e c t r o n - r i c h metal hydrides (5) with the resultant dihapto a c y l complexes. Such acyls obviously benefit from reduction of the CO bond order from three ( i n C=O) to two. More s i g n i f i cantly, the dihapto binding mode w i l l s i g n i f i c a n t l y enhance the e l e c t r o p h i l i c character of the a c y l carbon.
The e f f e c t o f w a t e r on e t h y l e n e g l y c o l p r o d u c t i o n i s p r o b a b l y q u i t e r e a l (21) b u t t h e c a u s e i s l e s s e v i d e n t . F. K i n e t i c I s o t o p e E f f e c t . 73 a t 180° i n p - d i o x a n e (13b) . ch002 25 2 0 2 2 2 ) o t o 2. FEDER ET AL. 25 Homogeneous Catalytic Mechanisms k φ kj) i t i s i m m e d i a t e l y e v i d e n t t h a t h y d r o g e n i s t r a n s f e r r e d i n o r b e f o r e t h e t r a n s i t i o n s t a t e and n o t , s a y , a n e l e c t r o n f o l l o w e d by a f a s t p r o t o n t r a n s f e r .
Catalytic Activation of Carbon Monoxide by Peter C., Ford