By Martin Malmsten
This new version beneficial properties study from approximately 60 of the profession's such a lot individual foreign experts. spotting rising advancements in biopolymer structures learn with totally up-to-date and accelerated chapters, the second one variation discusses the biopolymer-based multilayer constructions and their program in biosensors, the growth made within the knowing of protein behaviour on the air-water interface, experimental findings in ellipsometry and reflectometry, and up to date advancements touching on protein interfacial behaviour in microfabricated overall research platforms and microarrays. With over 3000 references, this is often a necessary reference for execs and scholars in floor, pharmaceutical, colloid, polymer, and medicinal chemistry; chemical, formula, and alertness engineering; and pharmacy.
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Additional info for Biopolymers at Interfaces, Second Edition (Surfactant Science Series)
Aspects 104:271–284 (1995). J. M. H. M. Scheutjens and G. J. Fleer, Statistical theory of the adsorption of chain molecules. I: Partition function, segment density distribution and adsorption isotherms. J. Phys. Chem. 83:1619–1635 (1979); II: Train, loop, tail size distribution 84:178–190 (1980). P. G. de Gennes, Polymer solutions near an interface. I: Adsorption and depletion layers. Macromolecules 14:1637–1644 (1981); II: Interaction between two plates carrying adsorbed polymer layers 15:492–500 (1982).
Also, similar to ﬂexible polymers, proteins may tend to spread over the sorbent surface. However, due to their relatively strong internal cohesion the spreading rate of proteins is far slower than that of ﬂexible polymers. If the rate of spreading is comparable to the rate of deposition at the surface, the extent of spreading (= conformation change) decreases with increasing ﬂux toward the surface and, as a consequence, the adsorbed mass will be larger. Such behavior has been observed for proteins [28,29], whereas under usual experimental conditions the spreading of ﬂexible polymers is much faster than the transport so that the adsorbed amounts are essentially independent of the ﬂux .
19 G. J. Fleer, M. A. Cohen Stuart, J. M. H. M. Scheutjens, T. Cosgrove, and B. Vincent, Polymers at Interfaces. Chapman & Hall, London, 1993. A. Johner and J. F. Joanny, Polymer adsorption in a poor solvent. J. Phys. II 1:181–194 (1991). M. A. Cohen Stuart and G. J. Fleer, Adsorbed polymers in nonequilibrium situations. Ann. Rev. Mat. Sci. 26:463–500 (1996). Z. Adamczyk, T. Dabros, J. Czarnecki, and T. G. M. van de Ven, Particle transfer to solid surfaces. Adv. Colloid Interface Sci. 19:183–252 (1983).
Biopolymers at Interfaces, Second Edition (Surfactant Science Series) by Martin Malmsten